本書(shū)內(nèi)容包括三部分,第一部分為基礎(chǔ)理論:介紹了晶體學(xué)、物理化學(xué)、高分子化學(xué)的基礎(chǔ)概念與原理;第二部分為材料應(yīng)用:介紹了金屬材料、無(wú)機(jī)非金屬材料和有機(jī)高分子材料的基本特性、制備方法;第三部分為材料保護(hù):介紹了各類(lèi)材料的腐蝕現(xiàn)象與防護(hù)措施。
Chapter 1 Foundation of Materials Science
1.2 Crystal Structures
1.1.1 Unit Cells
1.1.2 Crystal Systems
1.2 Crystalline and Nanocrystalline Materials
1.2.1 Single Crystals
1.2.2 Polycrystalline Materials
1.2.3 Anisotropy
1.2.4 Noncrystalline Solids
1.3 Defects
1.3.1 Point Defect
1.3.2 Linear Defects
1.3.3 Interfacial Defects
Questions
References
Chapter 2 Foundation of Physical Chemistry
2.1 Thermodynamic Laws
2.1.1 The First Law of Thermodynamics
2.1.2 The Second Law and the Third Law of Thermodynamics
2.2 Chemical Reaction Kinetics
2.2.1 Chemical Reaction and Rate Law
2.2.2 The Integral form of the Reaction Rate Equation
2.2.3 Linking the Rate Laws with Reaction Mechanisms
2.3 Electrochemical Foundation
2.3.1 Electrolyte Solution
2.3.2 Electrolyte System
2.3.3 Nernst Equation
2.3.4 The Electrochemical Reaction Rate
Questions
References
Chapter 3 Foundation of Polymer Materials
3.1 Introduction of Polymer
3.2 Classification of Polymers
3.2.1 Classification by Source
3.2.2 Classification by Application
3.2.3 Classification by Chain Structure
3.2.4 Classification by Thermal Behavior
3.2.5 Classification by Polymerization
3.2.6 Classification by Elemental Com□□□ition of Main Chain
3.3 Chain Structure and Condensed Structure
3.4 Glass Transition
Questions
References
Chapter 4 Preparation Principles in Materials Chemistry
4.1 Features of Basic Material
4.1.1 Metals
4.1.2 Ceramics
4.1.3 Polymeric Materials
4.1.4 Materials Design and Selection
4.2 Solid State Reaction
4.2.1 Definition and Features
4.2.2 Solid-solid Interface
4.3 Liquid State Reaction
4.3.1 Ostwald Ripening
4.3.2 Crystal Nucleation and Growth
4.4 Gas State Reaction
4.4.1 Vapor Absorption and Adsorption
4.4.2 Chemical Vapor De□□□ition (CVD)
4.4.3 Atomic Layer De□□□ition (ALD)
Questions
References
Chapter 5 Preparation Methods of Metal
5.1 Chemical and Photochemical Synthesis
5.1.1 Light Mediated Synthesis
5.1.2 Electrolysis and Pyrolysis
5.1.3 Citrate Reduction
5.1.4 Polyol Synthesis
5.1.5 Seed Mediated Synthesis
5.2 Soft and Hard Tem□□□te Mediated Synthesis
5.3 Hydrothermal Process
Questions
References
Chapter 6 Preparation Methods of Inorganic Nonmetallic Material ..
6.1 Preparation Methods of Inorganic Powders
6.1.1 Co-precipitation and Precursor Methods
6.1.2 The Sol-gel Method
6.1.3 Hydrothermal and Solvothermal Methods
6.1.4 Molten Salts
6.1.5 Combustion Synthesis
6.2 Molding Process of Inorganic Materials
6.2.1 Fabrication and Processing of Glasses
6.2.2 Powder Processing
6.2.3 Tape Casting
Questions
References
Chapter 7 Preparation Mechanisms of Polymer
7.1 Radical Chain Polymerization
7.1.1 Sequence of Radical Chain Polymerization
7.1.2 Kinetics of Initiation and Polymerization
7.2 Step-growth Polymerization
7.2.1 Self-catalyzed Polymerization
7.2.2 Molecular Weight of Polymer
7.3 Polymerization Processes
Questions
References
Chapter 8 Corrosion and Protection of Materials
8.1 Electrochemical Considerations
8.1.1 Electrode Potentials
8.1.2 The Standard EMF Series
8.1.3 The Galvanic Series
8.1.4 Corrosion Rates
8.2 Forms of Corrosion
8.2.1 Uniform Attack
8.2.2 Galvanic Corrosion
8.2.3 Crevice Corrosion
8.2.4 Pitting
8.2.5 Intergranular Corrosion
8.2.6 Erosion-corrosion
8.2.7 Stress Corrosion
8.2.8 Hydrogen Embrittlement
8.3 Protection Principles and Ways
8.3.1 Cathodic Protection
8.3.2 Anodic Protection
8.3.3 Corrosion Protection by Coatings
8.3.4 Change of Environment
8.3.5 Proper Design
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