本書是學(xué)術(shù)著作，反映了作者科研團(tuán)隊(duì)在石墨烯材料熱力學(xué)和電學(xué)性質(zhì)，特別是非簡諧效應(yīng)理論領(lǐng)域的研究成果。該書在介紹石墨烯材料的有關(guān)概念、分類和制備方法、普遍的物理化學(xué)性質(zhì)以及石墨烯的結(jié)構(gòu)和晶體結(jié)合的基礎(chǔ)上，論述非簡諧效應(yīng)理論的有關(guān)概念、基本觀點(diǎn)、研究問題的基本方法及其在三維、二維、納米系統(tǒng)熱學(xué)和電學(xué)性能等方面的一些應(yīng)用。該書基于石墨烯、外延石墨烯、類石墨烯等石墨烯材料的結(jié)構(gòu)以及組成粒子相互作用和運(yùn)動(dòng)特點(diǎn)，對(duì)石墨烯材料的熱力學(xué)和電學(xué)性能的變化規(guī)律及其非簡諧效應(yīng)，從理論上進(jìn)行深入的定量研究。該書突出了石墨烯材料的熱學(xué)和電學(xué)性能非簡諧效應(yīng)在高蓄熱材料器件、新能源、新器件、微電子、太赫茲、新型環(huán)境響應(yīng)材料等方面的應(yīng)用。該書的研究成果對(duì)石墨烯材料的研究和應(yīng)用具有重要的理論和實(shí)際意義。
內(nèi) 容 簡 介
本書反映了我們科研團(tuán)隊(duì)多年來在石墨烯材料熱力學(xué)和電學(xué)性質(zhì)，特別是非簡諧效應(yīng)理論領(lǐng)域的主要研究成果。在介紹石墨烯材料的有關(guān)概念、分類、制備方法、普遍的物理化學(xué)性質(zhì)以及石墨烯的結(jié)構(gòu)和晶體結(jié)合的基礎(chǔ)上，論述非簡諧效應(yīng)理論的有關(guān)概念、基本觀點(diǎn)、研究問題的基本方法及其在三維、二維、納米系統(tǒng)熱學(xué)和電學(xué)性能等方面的一些應(yīng)用。基于石墨烯、外延石墨烯、類石墨烯等石墨烯材料的結(jié)構(gòu)以及組成粒子的相互作用和運(yùn)動(dòng)特點(diǎn)，對(duì)石墨烯材料的熱力學(xué)和電學(xué)性能的變化規(guī)律及其非簡諧效應(yīng)，從理論上進(jìn)行深入的定量研究。突出了石墨烯材料的熱學(xué)和電學(xué)性能非簡諧效應(yīng)在高蓄熱材料器件、新能源、新器件、微電子、太赫茲、新型環(huán)境響應(yīng)材料等方面的應(yīng)用。本書對(duì)石墨烯材料的研究和應(yīng)用具有重要的理論和實(shí)際意義。
本書以理論研究為主，基礎(chǔ)理論有一定的深度和前沿性，系統(tǒng)性、邏輯性強(qiáng)，內(nèi)容次序符合認(rèn)知規(guī)律，突出了物理學(xué)科的學(xué)術(shù)特點(diǎn)，物理圖像清晰，物理思想明確，便于閱讀理解�？勺鳛閺氖率┎牧涎芯亢蛻�(yīng)用的研究人員和工程技術(shù)人員的參考書，也可作為材料、微電子等專業(yè)的教師、研究生的教學(xué)參考書。
目 錄
1 石墨烯材料簡介·································································· 001
1.1 石墨烯材料的起源及分類··············································· 001
1.1.1 石墨烯材料的起源················································ 001
1.1.2 石墨烯材料的分類················································ 004
1.2 石墨烯材料的基本性質(zhì)·················································· 007
1.2.1 石墨烯的力學(xué)性質(zhì)················································ 007
1.2.2 石墨烯的光學(xué)性質(zhì)················································ 008
1.2.3 石墨烯的化學(xué)性質(zhì)················································ 008
1.2.4 石墨烯的導(dǎo)電性··················································· 009
1.2.5 石墨烯的導(dǎo)熱性··················································· 010
1.2.6 石墨烯的阻隔性··················································· 010
1.3 石墨烯材料的制備方法簡介············································· 011
1.3.1 機(jī)械剝離法························································· 011
1.3.2 外延生長法························································ 013
1.3.3 氧化還原法························································ 014
1.3.4 溶劑熱法··························································· 019
1.3.5 有機(jī)合成法························································ 020
1.3.6 化學(xué)氣相沉積法··················································· 021
1.3.7 電弧放電法························································ 024
1.3.8 等離子增強(qiáng)合成法················································ 025
1.3.9 火焰法······························································ 027
參考文獻(xiàn)········································································· 029
...........
8.4 金屬基外延石墨烯熱電效應(yīng)的奇異現(xiàn)象······························· 303
8.4.1 金屬塊體基外延石墨烯的熱電勢······························· 303
8.4.2 金屬薄膜基外延石墨烯的熱電勢······························· 304
8.4.3 聲子拖拽對(duì)外延石墨烯熱電勢的貢獻(xiàn)·························· 306
8.5 石墨烯熱電性能的應(yīng)用·················································· 308
8.5.1 石墨烯熱電性能在新型環(huán)境響應(yīng)材料上的應(yīng)用·············· 308
8.5.2 石墨烯熱電性能在熱電器件上的應(yīng)用·························· 313
8.5.3 石墨烯熱電性能在光電探測器上的應(yīng)用······················· 315
參考文獻(xiàn)········································································· 317
附 錄················································································ 320
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